cis-Dichlorido(3,6,9-trithiabicyclo[9.3.1]pentadecane-κ2S3,S6)palladium(II) acetonitrile 0.8-solvate.
نویسندگان
چکیده
In the title complex, [PdCl2(C12H22S3)]·0.8CH3CN, a potentially tridentate thioether ligand coordinates in a cis-bidentate manner to yield a square-planar environment for the Pd(II) cation [mean deviation of the Pd from the Cl2S2 plane = 0.0406 (7) Å]. Each square-planar entity packs in an inverse face-to-face manner, giving pairs with plane-to-plane separations of 3.6225 (12) Å off-set by 1.1263 (19) Å, with a Pd···Pd separation of 3.8551 (8) Å. A partial acetonitrile solvent molecule is present. The occupancy of this molecule was allowed to refine, and converged to 0.794 (10). The synthesis of the previously unreported 3,6,9-trithiabicyclo[9.3.1]pentadecane ligand is also outlined.
منابع مشابه
Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate
In the structure of the title compound, [Pd(C(19)H(21)N(2)P)(2)](PF(6))(2)·2.85CH(3)CN, the two six-membered NHC-phosphane chelate rings form a distorted square-planar coordination geometry around the Pd(II) atom, which lies 0.212 (1) Å above the coordination plane. The sum of the bond angles at Pd(II) is 358.3°, with C-Pd-P bite angles of 84.03 (10) and 83.54 (9)°. The structure includes three...
متن کاملDichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2 N,N′)gold(III) tetrachloridoaurate(III) acetonitrile solvate
In the title compound, [AuCl(2)(C(9)H(12)N)(2)][AuCl(4)]·C(2)H(3)N, there is a mirror plane passing through Au and the central C-C bond of the bipyridyl ligand in the cation, and through Au and two Cl atoms of the anion. A cis-AuCl(2)N(2) square-planar geometry for the cation and a square-planar AuCl(4) geometry for the anion result. The two C atoms and the N atom of the acetonitrile mol-ecule ...
متن کاملSynthesis, structural studies, kinetic stability, and oxidation catalysis of the late first row transition metal complexes of 4,10-dimethyl-1,4,7,10-tetraazabicyclo[6.5.2]pentadecane.
Synthetic details for 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.5.2]pentadecane, the dimethyl ethylene cross-bridged homocyclen ligand are presented for the first time. Its novel Mn(2+), Fe(2+), Mn(3+), and Fe(3+) complexes have been synthesized and characterized. X-ray crystal structures were obtained for both manganese complexes, along with five additional Co(3+), Cu(2+), and Zn(2+) structures...
متن کاملcis-Dichlorido[4,4,5,5-tetramethyl-2-(2-pyridyl)-2-imidazoline-1-oxyl]palladium(II) tetrahydrofuran hemisolvate
The asymmetric unit of the title complex, [PdCl(2)(C(12)H(16)N(3)O)]·0.5C(4)H(8)O, consists of one palladium complex in a general position and one half tetra-hydro-furan (THF) solvent mol-ecule, with the O atom lying on a twofold rotation axis. The Pd(II) atom is bound to one chelating imino nitroxide radical through two N atoms, one from the pyridyl ring and the other from the imidazoline ring...
متن کاملC 2-isomer of [Pd(tfd)]6 [tfd is S2C2(CF3)2] as its benzene solvate: a new member of the small but growing class of homoleptic palladium(II) monodithiolenes in the form of hexameric cubes
The title compound, hexa-kis-[μ3-1,2-bis-(tri-fluoro-meth-yl)ethene-1,2-di-thiol-ato]-octa-hedro-hexa-palladium(II), [Pd(C4F6S2)]6, crystallizes as its benzene solvate, [Pd(tfd)]6·2.5C6H6, where tfd is the di-thiol-ene S2C2(CF3)2. The mol-ecular structure of [Pd(tfd)]6 is of the hexa-metallic cube type seen previously in three examples of hexa-meric homoleptic palladium monodi-thiol-ene structu...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Acta crystallographica. Section C, Crystal structure communications
دوره 69 Pt 7 شماره
صفحات -
تاریخ انتشار 2013